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The images on the cover call attention to the relationship between macro observations and the intimate structure of chemical substances and the changes, both chemical and physical, that they undergo. Fireworks: One of the ingredients is phosphorus, a molecular form of which is believed to consist of linked tetrahedra of phosphorus atoms. The chemical reaction of phosphorus with oxygen is partly responsible for the spectacular show of light. Carbon: The element is found in several forms, including the familiar diamond and another, recently discovered, sooty substance that consists of soccer-ball shaped molecules, often referred to as "buckeyballs." Diamond is not the most stable form of carbon and is created from other forms of carbon at high temperatures and pressures deep within the earth. Acetylene torch: Cutting steel is possible because of the intense heat generated by the chemical reaction of acetylene with oxygen, a reaction between molecules of C_2H_2 and O_2 to give CO_2 and H_2O. Hot air balloon: The air that helps it rise is heated by the combustion of molecules of propane, each composed of three carbon and eight hydrogen atoms. Stormy weather: The evaporation of water serves to store energy provided by the sun. Subsequent condensation of the water vapor releases this energy and is the basis of all the weather systems on our planet.
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This new edition of Robert G. Mortimer's Physical Chemistry has been thoroughly revised for use in a full year course in modern physical chemistry. In this edition, Mortimer has included recent developments in the theories of chemical reaction kinetics and molecular quantum mechanics, as well as in the experimental study of extremely rapid chemical reactions. While Mortimer has made substantial improvements in the selection and updating of topics, he has retained the clarity of presentation, the integration of description and theory, and the level of rigor that made the first edition so successful. * Emphasizes clarity; every aspect of the first edition has been examined and revised as needed to make the principles and applications of physical chemistry as clear as possible. * Proceeds from fundamental principles or postulates and shows how the consequences of these principles and postulates apply to the chemical and physical phenomena being studied. * Encourages the student not only to know the applications in physical chemistry but to understand where they come from. * Treats all topics relevant to undergraduate physical chemistry.
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